1-(4-Chloro­phen­yl)piperazine-1,4-diium tetra­chlorido­zincate(II) monohydrate

نویسندگان

  • Imen Ben Gharbia
  • Riadh Kefi
  • Meher El Glaoui
  • Erwann Jeanneau
  • Cherif Ben Nasr
چکیده

In the crystal structure of the title compound, (C(10)H(15)ClN(2))[ZnCl(4)]·H(2)O, the Zn atom is coordinated by four Cl atoms in a tetrahedral geometry. The water mol-ecules and the 1-(4-chloro-phen-yl)piperazine-1,4-diium cations inter-act with the [ZnCl(4)](2-) anions through O-H⋯Cl, N-H⋯Cl, N-H⋯O and C-H⋯Cl hydrogen bonds (five simple and one bifurcated). Inter-molecular π-π stacking inter-actions are present between adjacent aromatic rings of 1-(4-chloro-phenyl)-piperazine-1,4-diium cations (the centroid-centroid distance is 3.453 Å).

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

1-Diphenyl­methyl-4-[3-(4-fluoro­benzo­yl)prop­yl]piperazine-1,4-diium dichloride monohydrate

In the title compound, C(27)H(31)FN(2)O(2+)·2Cl(-)·H(2)O, the piperazine ring adopts a chair conformation and both N atoms are protonated. The Cl(-) anions form strong hydrogen bonds to these protons. O/N-H⋯Cl and C-H⋯O hydrogen bonds link the anions, cations and water of hydration into a three-dimensional network.

متن کامل

1-(2,5-Dimethyl­phen­yl)piperazine-1,4-diium tetra­chloridozincate monohydrate

In the title compound, (C(12)H(20)N(2))[ZnCl(4)]·H(2)O, the two piperazine N atoms are protonated and the [ZnCl(4)](2-) anions adopt a slightly distorted tetra-hedral configuration. In the crystal, O-H⋯Cl hydrogen bonds link the tetra-chloridozincate anions and the water mol-ecules into corrugated inorganic chains parallel to [010]. The crystal structure is stabilized by N-H⋯Cl, N-H⋯O and O-H⋯C...

متن کامل

1-(4-Hy­droxy­phen­yl)piperazine-1,4-diium tetra­chlorido­cobalt(II) monohydrate

The asymmetric unit of the title inorganic-organic hybrid compound, (C10H16N2O)[CoCl4]·H2O, consists of a tetrahedral [CoCl4](2-) anion, together with a [C10H18N2O](2+) cation and a water mol-ecule. Crystal cohesion is achieved through N-H⋯Cl, O-H⋯Cl and N-H⋯O hydrogen bonds between organic cations, inorganic anions and the water mol-ecules, building up a three-dimensional network.

متن کامل

1-[4-(3-{[5-(4-Chloro­phen­yl)furan-2-yl]methyl­idene­amino}-2,5-dioxoimidazol­idin-1-yl)but­yl]-4-methyl­piperazine-1,4-diium dichloride hemihydrate

The title compound, C(23)H(30)ClN(5)O(3) (2+)·2Cl(-)·0.5H(2)O, was synthesized by N-alkyl-ation of 1-({[5-(4-chloro-phen-yl)-2-furan-yl]methyl-ene}amino)-2,4-imidazolidinedione with 1-bromo-4-chloro-butane, and N-methyl-piperazine. In the crystal, the cations, anions and water mol-ecules are linked by O-H⋯Cl and N-H⋯Cl hydrogen bonds.

متن کامل

Piperazine-1,4-diium 2-(carb­oxy­meth­yl)-2-hy­droxy­butane­dioate monohydrate

In the crystal structure of the title compound, C(4)H(12)N(2) (2+)·C(6)H(6)O(7) (2-)·H(2)O, the cations, anions and water mol-ecules are linked by inter-molecular N-H⋯O, O-H⋯O and weak C-H⋯O hydrogen bonds into a three-dimensional network. An intra-molecular O-H⋯O inter-action occurs in the dianion.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008